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IIT JEE Purification Of Organic Compounds .
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IIT JEE Purification Of Organic Compounds .
1
A substance which decomposes below it s boiling point can be best purified by
A
Simple distillation
B
Steam distillation
C
Fractional distillation
D
Distillation under reduced pressure.
2
0.1914g of a monobasic organic acid is dissolved in about 20 mL of water 25 mL of 0.12 M NaOH is required for complete neutralization of the acid solution. The molar mass of the acid is65.0
A
65
B
64
C
62.5
D
63.8.
3
The boiling point of a compound does not depend upon
A
Solubility of the compound in water
B
Hydrogen bonding
C
Size of molecules
D
Polarity of the molecule.
4
A mixture of camphor and benzoic acid can be separated by which of the following technique?
A
Chemical methods
B
Sublimation
C
Fractional distillation
D
Extraction with a solvent.
5
A mixture of acetone and methanol can be separated by
A
Vacuum distillation
B
Steam distillation
C
Fractional distillation
D
Simple distillation.
6
The purification of benzeneamine is done by
A
Steam distillation
B
Chromatographic techniques
C
Fractional crystallisation
D
By adding oxalic acid.
7
By decreasing the pressure the boiling point of a liquid
A
Increases
B
Decreases
C
Remains constant
D
May increases or decrease.
8
Sublimation cannot be used for purification of
A
Naphthalene
B
Camphor
C
Benzoic acid
D
Urea.
9
0.532 g of the chloroplatinate of an organic base (mol. Mass 264) gave 0.195 g Pt on ignition. Then the number of nitrogen atoms per molecule of the base is
A
1
B
2
C
3
D
4
10
In Lassaignes test the organic compound is fused with a piece of sodium metal in order to
A
increase the ionization of the compound
B
decrease the melting point of the compound
C
increase the reactivity of the compound
D
convert the covert the covalent compound into a mixture of ionic compounds.
11
The formation of violet colour when sodium nitroprusside is added to sodium extract indicates the presence of.
A
Nitrogen
B
Sulphur
C
Oxygen
D
Halogens
12
The Beilsteins test is a rapid test used for organic compounds to detectSulphur
A
Phosphorus
B
Sulphur
C
Halogens
D
Nitrogen.
13
When a solid vapourize directly without melting the process is calledEvaporation
A
Evaporation
B
Sedimentation
C
Saponification
D
Sublimation.
14
In paper chromatography
A
the mobile phase is a liquid and the stationary phase is a solid
B
the mobile phase is a solid and the stationary phase is a liquid
C
both phases are liquids
D
both phases are solids.
15
A mixture of benzoic acid and naphthalene can be separated by crystallization from
A
Hot water
B
Cold water
C
Benzene
D
Ether.
16
Chromatographic technique was introduced by
A
Duma (1803)
B
Kjeldhl (1903)
C
Tswett (1906)
D
Lavosier.
17
Naphthalene can be purified by
A
Sublimation
B
Crystallization
C
Extraction with a solvent
D
Distillation.
18
Sugar containing an impurity of common salt can be purified by crystallization from
A
Benzene
B
Ethanol
C
Petroleum ether
D
Water.
19
A mixture of o-hydroxyacetophenone and hydroxyacetophenone can be separated by.
A
Sublimation
B
Steam distillation
C
Fractional crystallization
D
Distillation
20
Separation of two substances by fractional crystallisation depends upon their difference inMelting point
A
Densities
B
Solubilities
C
Melting point
D
Boiling points.
21
The formation of violet colour when sodium nitroprusside is added to sodium extract indicates the presence of
A
Nitrogen
B
Sulphur
C
Oxygen
D
Halogens.
22
The Beilsteins test is a rapid test used for organic compounds to detect
A
Phosphorus
B
Sulphur
C
Halogens
D
Nitrogen.
23
When a solid vapourize directly without melting the process is called
A
Evaporation
B
Sedimentation
C
Saponification
D
Sublimation.
24
Naphthalene can be purified by
A
Sublimation
B
Crystallization
C
Extraction with a solvent
D
Distillation.
25
A mixture of o-hydroxyacetophenone and hydroxyacetophenone can be separated by
A
Sublimation
B
Steam distillation
C
Fractional crystallization
D
Distillation.
26
Separation of two substances by fractional crystallisation depends upon their difference inBoiling points.
A
Densities
B
Solubilities
C
Melting point
D
Boiling points.
27
Which of the following element s in an organic compound cannot be detected by Lassaignes test?
A
N
B
S
C
Cl
D
H.
28
The separation an organic compound from it s aqueous solution can be achieved by:Steam distillation
A
Distillation
B
Steam distillation
C
Solvent extraction
D
Fractional distillation.
29
0.59 g of the silver salt of an organic acid (mol. Mass 210) on ignition gave 0.36 of pure silver. The basicity of the acid is1234.
A
1
B
2
C
3
D
4
30
In steam distillation the sum of the vapour pressure of the volatile compound and that of water is
A
equal to atmospheric pressure
B
less than atmospheric pressure
C
more than atmospheric pressure
D
exactly half of the atmospheric pressure.
31
The separation of the constituents of a mixture by column chromatography depends upon their
A
Different solubilities
B
Different boiling points
C
Different refractive indices
D
Differential adsorption.
32
Refining of petroleum involves the process ofFractional distillation
A
Simple distillation
B
Fractional distillation
C
Steam distillation
D
Distillation under reduced pressure.
33
The technique of gas chromatography is suitable for compounds which
A
are liquids
B
have very low boiling points
C
are soluble in water
D
vapourize without decomposition.
34
Steam distillation is used for the extraction of
A
Essential oils
B
Higher alkynes
C
Mineral oils
D
Fatty acids.
35
A compound which does not give a positive test in the Lassaignes test for nitrogen isUrea
A
Urea
B
Hydroxyl amine
C
Glycine
D
Phenylhydrazine.
36
Haemoglobin contains 0.33% of iron by mass. The molecular mass of haemoglobin is approximately 67200. The number of iron atoms [at. mass Fe = 56] present is one molecule of haemoglobin is6142.
A
6
B
1
C
4
D
2
37
An organic compound having carbon hydrogen and sulphur contains 4% of sulphur. The minimum molecular mass of the compound is
A
200
B
400
C
600
D
800
38
Certain organic compound contains 10% of sulphur is it. Which of the following represent the minimum molecular mass of the compound
A
320
B
160
C
400
D
200
39
The chloroplatinate of an organic base contains 39% of Pt. The equivalent mass of the base is
A
73
B
59
C
65
D
45
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